Polymers
In view of their versatile properties polymers are called wonder materials.
They have substituted traditional materials such as metal, glass, wood &
concrete either fully or partially in most of the end use applications.
Material Science Division has always been involved in contemporary research
and has developed, modified & commercialized a number of processes over
the years. The am,in areas in which MSD deals are:
- Polymer blends /Alloys
- Composites
- Adhesives, coatings & lacquers
- Healthcare & Bio materials
- Optimization of polymer processing parameters
- Scaling up of technologies from lab to pilot scale and
eventually commercialization
- Plastic waste utilization
- Modification of existing processes and import substitutes
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Polymer Synthesis
Polymer synthesis involves several aspects of synthetic chemistry. In order
to develop polymers of desired characteristics, control of process
parameters are very important specially when the product is meant for health
care and food industries. MSD undertakes projects for the synthesis of novel
materials for various applications or develops alternate materials for
different applications.
Some of the recent projects undertaken on the synthesis are listed below:
- Synthesis of metal containing polyacrylates for optical
applications. Metal containing polyacrylates have been developed
with excellent physico- mechanical and optical properties.
- Synthesis of high refractive index novel polythiols for optical
application Optimization of process parameters has been carried out
to synthesize colorless polythiols. Casting into colourless impact
resistant, transparent and bubble free sheets has been carried out
successfully for application in high refractive index lens.
- Synthesis of polyglycolic acid based surgical absorbable sutures
Polyglycolic acid was prepared through the synthesis of an
intermediate glycolide by ring opening polymerization
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Development of Bone Cement
Bone cement is used to fill the gap between bone and prosthesis. Bone
cement has been prepared on laboratory scale and physico-mechanical
properties were found to be conforming to the international standard.
Development of Dental Cement
Polycarboxylate based dental cement used for filling dental cavities,
fixation of crown, bridges and also as luting agent has been successfully
developed as per international standard.
Polymer Characterization
Material Science Division has the competency to characterize the polymer
and blends/compounds to identify major constituents in polymeric
compositions. Highly competent manpower with state-of-the-art equipment for
characterization of polymers help the industry in the following ways:
Physical & Mechanical Characterization
- Hardness
- Density
- Dimensional stability
- Flame retardance
- Burning Characteristics
- Tensile strength
- Flexural strength
- Impact strength
- Compressive strength
- Youngâs Modulus
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Thermal Characterization
- Hardness
- Density
- Dimensional stability
- Flame retardance
- Burning Characteristics
- Tensile strength
- Flexural strength
- Impact strength
- Compressive strength
- Youngâs Modulus
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Rheological Characterization
- Viscosity
- Stress - strain behavior
- Melt elasticity parameters
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Electrical characterization
- Dielectric constant
- Volume resistivity
- Dissipation factor
- Surface resistivity
- Breakdown voltage
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Polymer Compounding
Based on the desired performance criteria and applications, experts of SRI
can design special polymer compounds. Sufficient experience and expertise
exists for compounding of various resins of PVC, PP, PE, PS, ABS, PC and
rubber blends with various additives such as plasticizers, stabilizers,
lubricants and specialty additives etc. for development of various products:
- Cables for high performance applications
- PVC Flooring for household and industrial applications
- PVC Shoe soles with high abrasion resistance
- Automotive components
- Healthcare products such as blood bag, CAPD bag, body warmer
bag, Catheter etc.
- Plastic wares for medical and biomedical applications
- Radiation resistant compositions for specialty applications
- Consumer items such as cling films, anti-rodent &
anti-termite films etc.
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Polymer Processing
Pilot Plant of Material Science Division is well equipped with major
polymer processing equipment which are used for optimization of process
parameters of various polymeric materials such as:
- Commodity plastics
- Engineering plastics
- Rubber compounds
- Thermosets
- Thermoplastic elastomers
- Polymeric blends
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Assignments for finalizing the process parameters, based
on which suitable products can be developed, using different types of
polymeric substances. The expertise can be used not only for developing
processes for new products but also for making the cost-effective
formulations using alternative raw materials.
Polymer Modification
Polymer modifications are at times necessary to generate certain specific
functionalities in the standard materials. Using the expertise and the
knowledge, the scientists of SRI can help the users by modifying the
polymers as per the needs of their applications. Methods of tailor making of
polymers for various end applications in which SRI has enough experience are
listed below:
- Compounding
- Grafting
- Alloying & blending
- Surface modification
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Weathering Studies
Polymers have to perform in a variety of hostile conditions which varies
from very cold to very hot & humid. SRI has infrastructure and expertise
to carry out weathering studies in artificially simulated conditions of
exposure to ultraviolet rays.
SRI has worked on weathering studies of:
- EPDM/PVC compositions in solar cell
- EPDM/PP compositions for automotive applications
- Weather resistant PVC compositions for cooling towers
- Neoprene coated nylon fabric
- HDPE woven sacks
- Color fastness of coatings & textiles
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Polymer Applications
Medical products Polymers are the most important and largest family
of materials being used in medical applications. Polymers have various
advantages such as lightweight, easy processability and reproducibility,
non-toxicity, biocompatibility and good aesthetics. Because of these
advantages, polymers are used in the various medical devices such as
artificial limbs, wound dressing, artificial skin, blood bag, CAPD bag,
bioprosthetic heart valve, various replacement joints, bioabsorbable suture,
contact and intraocular lenses, orthodontic devices, tissue adhesive,
bandages and drug carrier & implants.
SRI has expertise to develop desired product or a product equivalent to the
best in the market.
Major R&D Projects SRI has successfully developed various
polymer based products for medical applications.
Blood bagSRI has developed blood bag composition having
physico-mechanical as well as hematological properties conforming to ISO
3826.
CAPD system for Continuous Ambulatory Peritonial Dialysis SRI has
developed CAPD system with dialysate solution and its physico-mechanical as
well as toxicological properties are comparable with the standard available
product.
Technology for production of bone cement and bone substitute Bone
cement is used to fill the gap between bone and prosthesis. Bone cement has
been prepared on laboratory scale and physico-mechanical properties viz.
dough time, setting time, bending modulus and compressive strength are
comparable to the imported product.
Vaginal Speculum Disposable vaginal speculum has been developed for
gynaecological applications. These can replace metallic speculum, which
needs to be sterilized for long periods and pose risks of disease
transmission if improperly sterilized.
Body warmer SRI has developed heat releasing chemical composition
along with heat stable polymer film for body warmer bag. Bag is ideally
suited for applications such as orthopedic heating pad for body fomentation,
heating pad for baby nursery, instant heating for automobile engine etc.
Low cost disposable medical hygiene products A technology for the
manufacture of low cost disposable healthcare products viz. diapers and
sanitary napkins have been developed.
Synthesis of novel polythiols Optimization of process parameters has
been carried out to synthesize colorless polythiol. Casting of polythiol
into colorless impact resistant, transparent and bubble free sheets has been
carried out successfully for application in high refractive index lens.
Polyglycolic acid (PGA) based synthetic absorbable sutures Processes
for synthesizing glycolide & polyglycolic acid (PGA) have been
developed. The synthesized PGA was found comparable to imported PGA.
Consumer Products Because of the inherent benefits associated with
plastics, they are widely used in manufacturing of various products such as
consumer products and in packaging applications. Some of the consumer
products developed at SRI:
Cling film Polyethylene based single/multi-layered cling film was
developed for both industrial and food packaging applications.
Rodent Repellent PVC and PE compositions Rodent repellent PVC and PE
compositions laminated with jute fabric have been developed for storage of
grains in godowns
Abrasion resistant low cost shoe soles PVC/PU blends and PVC/NBR
blends have been developed for abrasion resistant low cost shoe soles
conforming to IS specifications
PVC compositions for floor tiles Cost effective, highly filled
calenderable PVC compositions were developed for floor tiles application.
High performance cables PVC and PE based compositions crosslinkable
by electron beam have been developed for high performance cables
Plastic Waste Utilization The rapid rate of industrialization and
urbanization has led to increasing amount of industrial as well as municipal
waste. This in turn poses great difficulties in managing the disposal of
such type of waste. Keeping in view the environmental hazards associated
with plastic, there is an urgent need of eco friendly ways for utilization
of such type of waste.
SRI has successfully developed eco friendly ways for utilization of plastic
waste in the following areas
Process Engineered Fuels (PEFs) from plastic wastes Process
engineered fuels with different calorific values have been developed from
plastic and agri wastes, which may be used in boilers, furnaces and kilns.
Road construction Composition comprising bitumen, concrete and
plastic wastes were developed for road construction having better properties
than the conventional bituminous road.
Value added products Plastic furniture made from waste material with
good durability and aesthetics have been developed.
Poly pallet developed at SRI was found excellent substitute of wood pallets
for stacking of sacks.
Composites A Composite is a combination of two or more dissimilar
materials resulting in superior properties from those of the starting
materials. Composites consist of a reinforcing agent, a matrix resin for
binding and adhesion promoters and a variety of fillers. Composites are
lightweight and have high performance to weight ratio. The reinforcing
agents are used in fibrous form and include natural fibers such as jute &
silk, organic fibers such as carbon & aramid fibers and synthetic
inorganic fibers which include glass, silicon carbide, silicon tri nitride
and alumina.
Major R & D Projects SRI has expertise to
develop composites for various applications. Some of the polymer composites
developed are:
Fire retardant jute composite Jute composites have been prepared by
replacing polyester and polystyrene with natural Euphorbia latex coagulum.
Water absorption properties of polyester coagulum composites are better than
polystyrene coagulum composites. This composite can be successfully used as
wood substitute.
Mesta fiber composite Composites of polypropylene/mesta fibre with
good physico-mechanical properties have been developed. This composite may
find applications in window profile and automotive application.
Insulated laminated boards Fire retardant and antistatic laminates
were developed using ceramic fibre along with polyester resin. Floor tiles
were prepared by dough moulding and compression moulding.
Wood polymer composites Wood polymer composites based on inferior
wood species have been developed with properties comparable or better than
teak.
Anti-fungus, anti-rodent PVC/ PE compositions Anti-fungus,
anti-rodent PVC /PE composition for lamination on jute fabric was developed.
Toxicological studies revealed these to be non-toxic. These can be used as
flooring material in food storage godowns and will help in saving of
considerable amount of food grains from destruction by rodent or fungal
attack.
Organic Synthesis Shriram Institute has the necessary capabilities
and expertise in the synthesis of various types of organic chemicals.
Several projects based on synthetic chemistry have been taken up in the past
and others are in progress. These include:
- Sebacic acid
- Epoxidised Diallyl phthalate
- Organotitanates
- Fluorinated lubricating oils
- Polycarbonate
- Polyglycolic acid
- Polythiols
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Specialty Chemicals SRI undertakes research for
the development of specialty chemicals, which finds numerous applications in
different areas, which include process technology, green technology and
formulation development The application areas are:
- Adhesives
- Coatings
- Defoamers
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Adhesives Adhesives are used to bond two similar
or dissimilar surfaces to achieve the desired strength. Material Science
Division takes up assignments on the development of various hot melt,
solution and water based adhesives for different applications as per the
requirement of the customer
SRI has successfully developed many adhesives for various applications.
Some of the formulations developed are:
Water based adhesive Water based adhesive has been developed for
tyre retreading in the form of a stable aqueous dispersion. The developed
adhesive is comparable in strength, tack, shelf-life, drying time vis-Ã
-vis solvent based adhesive with better coverage.
Hot melt adhesive Hot melt adhesive for book binding application has
been developed with good tack and easy processing.
Glue stick Glue stick was developed for stationary use, which was
found comparable with the leading available brands in respect of adhesion,
tack free time and compactness
Coatings Coatings are used to provide protection, aesthetics and
value addition to substance/substitutes. SRI has successfully developed
coating for different applications
Major R&D Projects Some coating formulations developed by SRI
are as follows:
Surface coating formulations for wood laminates Acrylate based high
performance electron beam curable surface coating formulation for wood
laminates/boards has been developed which offer superior combination of
properties and versatility of performance.
Water repellent coating for glass Highly effective water and dust
repellent coating formulation for glass was developed using indigenous raw
materials, which find application in window panels for high rise buildings
and windshield of cars.
Road marking paint SRI has successfully developed road-marking
paint, used to draw lines on the road, which is long lasting, luminescent,
weather and friction resistant
Defoamer Defoamers are used to suppress the foam generated during
the production of emulsions in various applications including food, pharma
and chemical industries.
SRI has successfully developed a defoamer formulation for fertilizer
industries to kill the huge foam generated during the digestion of phosphate
rock with sulphuric acid for the manufacture of fertilizer. A cost-effective
formulation of defoamer from indigenous raw materials has been developed.
SRI can develop defoamers based on silicone and non-silicone raw materials
for various industrial applications.
Herbal Products Material Science Division is actively involved in
the area of herbs with medicinal value and economic benefit.
The R&D areas include:
- Formulation development
- New product development
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Major R&D projects
- Retention of color fastness in henna cones on storage
- Phytoremediation of arsenic in ground water
- Extraction process for hypericin from hypericum plant
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Several projects related to the quality evaluation of
herbal products are being actively pursued by the Drug and Pharmaceutical
section of Biology Division of SRI.
Renewable Resources In view of the excessive utilization and
continuous depletion of petroleum reserves, SRI is involved in the
development of products based on renewable natural resources as substitute
of petroleum derived products. These include:
Organic active extraction
- Bio-diesel
- Eco-friendly composites
- Bio- degradable fibers/ polymers
- Natural mordants for dyeing with natural dyes
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Major R&D Projects Some of the projects based
on renewable sources undertaken by SRI include:
Anti-oxidants from natural source SRI has successfully isolated
natural antioxidant gum guaiac from Guaiacum officianale plant. Antioxidant
effectiveness of isolated gum guaiac in fats/oils was found comparable with
commercial antioxidant.
Epoxidised oil from plant seeds Epoxidised oil was extracted from
seeds of Vernonia plant. This naturally epoxidised oil can be used as
plasticizer/stabilizer in PVC based compositions replacing synthetically
produced epoxidised soyabean oil.
Cardanol from cashew nut shell liquid
A distillation process has been developed to recover 90% cardanol, which is
light in color and does not darken upto one month.
Radiation Based Technologies Irradiation technology finds
applications in processing of food, agriculture products, healthcare and
cosmetic products, crosslinking of wires and cables, and modification of
polymers for various end use.
Major R & D Projects SRI has worked on following radiation-based
technologies:
Shelf-life enhancement of fruits Optimization of gamma radiation
doses for shelf-life enhancement of apples has been carried out. Irradiation
increases shelf-life by delaying the ripening process.
Detoxification of aflatoxin in peanuts Toxic aflatoxin metabolites
which are carcinogenic are found in peanuts. Irradiation of peanuts by UV
and gamma rays has been able to detoxify the aflatoxin.
Epoxy based composites by electron beam curing process Glass
fibre-Epoxy composites with superior mechanical & thermal properties
have been developed for automobiles and aircraft applications.
Wood polymer composites Wood polymer composites based on inferior
wood species have been developed with properties comparable to or better
than teak.
Remediation of polychlorinated biphenyls (PCBs) Polychlorinated
Biphenyls found in oil, capacitors and paint scrapings of old ships have
been radiolysed by gamma irradiation.
Surface coating formulations for wood laminates The high performance
electron beam curable surface coating formulation for wood, wood
laminates/boards based on 100% solid acrylate offer superior combination of
properties leading to versatility of performance.
Treatment of city sewage by radiation Effect of gamma radiation
treatment on sewage was studied. Reduction in microbiological load (BOD and
COD) in waste sewage was achieved by gamma irradiation. Improvement in the
settling time of waste was also observed.
PVC compounds for wire and cable industry Crosslinking in PVC
compounds was achieved using gamma irradiation. Crosslinked PVC compound was
found to have good thermo-mechanical properties.
Colouration of Gem-stones Different colours in gem stones were
achieved by exposing them at various radiation doses.
Waste Utilization
Plastic WasteThe rapid rate of industrialization and urbanization
has led to increasing amount of industrial as well as municipal waste, which
poses great difficulties in its disposal. Keeping in view the environmental
hazards associated with the plastic, there is an urgent need to develop eco-
friendly ways for utilization of such type of waste.
SRI has successfully developed various ecofriendly ways for utilization of
plastic waste which include:
Process Engineered Fuels (PEFs) from plastic wastes Process
engineered fuels with different calorific values have been developed from
plastic and agri wastes, which may be used in boilers, furnaces and kilns.
Road construction Composition comprising bitumen, concrete and
plastic wastes were developed for road construction having better properties
than the conventional bituminous road.
Value added products Plastic furnitures made from waste material
with good durability and aesthetics have been developed.
Polypallets developed at SRI were found excellent substitute of wood
pallets for stacking of sacks.
Agro Waste SRI has been undertaking projects for utilization of
various agro wastes. Some of the projects undertaken are:
Precipitated silica from rice husk ash Rice husk ash poses
environmental problem while disposed off. SRI has developed technology to
make silica from this waste material.
Microcrystalline cellulose from ground nut shell The shells of
peanuts are useless and are environmental hazard. SRI has successfully
developed technology for making microcrystalline cellulose from this waste.
Industrial Waste Lots of industrial wastes are generated in process
and production industries which poses environmental problem. SRI has been
undertaking projects for value addition in an environment friendly way. Some
of the projects undertaken in this field are:
1. Ordinary portland cement from flyash Flyash is considered to be a
potential environmental hazard when disposed off. This has been successfully
used in cement compositions without impairing the performance of the cement.
2. Tiles from ceramic fiber waste Waste ceramic short fibers
creating environmental problem are used to make antistatic floor tiles with
good aesthetics.
Technology Business
Incubator
Shriram Institute is in the process of setting up a Technology Business
Incubator shortly. Since there are plenty of small scale plastic and rubber
processing industries as well as new entrants are coming up who do not have
adequate technical backup but have financial strength and zeal to start a
new industry, there is a need to setup a TBI that can provide suitable
infrastructure as well as know how to these industries. Besides promoting
new entrepreneurs, it is essential for the existing industries to regularly
upgrade the knowledge of their man power. The proposed TBI will become a
centre for technical training to the personnel working in sindustries.
Objectives of TBI
- To develop new entrepreneurs.
- To organise awareness / orientation and entrepreneurs development
programme.
- To provide training to the entrepreneurs and work force of the
industries.
- To create avenues for employment to the people and expanding the
existing level of knowledge.
- To identify the struggling industries falling in the thrust
areas.
- To support these industries in making them competitive with
respect to product quality, price, output and process waste
utilization.
- By optimizing the existing process with respect to suitable raw
material selection, formulation and waste minimization.
- By indigenising the manufacturing process with the aim to save
the foreign exchange.
- By exploring the possibility for conversion of industrial waste
into a value added product.
- By substituting the existing process with eco-friendly
manufacturing process.
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